PUBLICATIONS
2024
49. F. Caporaletti, L. Gunkel, M. Á. Fernández-Ibáñez, J. Hunger, S. Woutersen, ‘‘Fast Collective Hydrogen-Bond Dynamics in Hexafluoroisopropanol Related to its Chemical Activity” Angew. Chem. Int. Ed., 2024, e202416091
48. K.-Z. Deng, M. Á. Fernández-Ibáñez, ‘‘Process for Producing a Compound Having at least Two Aryl Moieties” PATENT EP 24180149.7.
47. K.-Z. Deng, V. Sukowski, M. Á. Fernández-Ibáñez, ‘‘Non-directed C-H Arylation of Anisole Derivatives via Pd/S,O-Ligand Catalysis’’ Angew. Chem. Int. Ed., 2024, e202400689
46. V. Sukowski, M. van Borselen, S. Mathew, B. de Bruin, M. Á. Fernández-Ibáñez, ‘‘meta -C-H Arylation of Aniline Derivatives via Palladium/S,O-Ligand/Norbornene Cooperative Catalysis’’ Angew. Chem. Int. Ed., 2024, 63, e202317741
2023
45. K. Naksomboon, E. Gómez-Bengoa, J. Mehara, J. Roithová, E. Otten, M. Á. Fernández-Ibáñez, ‘‘Mechanistic studies of the palladium-catalyzed S,O-ligand promoted C-H olefination of aromatic compounds’’ Chem. Sci., 2023, 14, 2943. Advance Article.
2022
44. P. Riente, W.-L. Jia, M. Á. Fernández-Ibáñez, ‘‘Pd-Catalyzed C-H Olefination Reactions’’. In Handbook of C-H functionalization, D. Maiti (Ed.), 2022, ISBN: 9783527834242
43. V. Sukowski, M. van Borselen, S. Mathew, M. A. Fernández-Ibáñez, ''S,O-Ligand Promoted meta-C–H Arylation of Anisole Derivatives via Palladium/Norbornene Catalysis’’ Angew. Chem. Int. Ed. 2022, 61, e202201750
42. K.-Z. Deng, W.-L. Jia, M. Á. Fernández-Ibáñez, ''Selective para-C–H Alkynylation of Aniline Derivatives via Pd/S,O-Ligand Catalysis''Chem. Eur. J. 2022, 28 e202104107
2021
41. V. Sukowski, W.-L. Jia, R. van Diest, M. van Borselen, M. Á. Fernández-Ibáñez, ''S-O-ligand-Promoted Pd-Catalyzed C-H Olefination of Anisole Derivatives''Eur. J. Org. Chem. 2021, 29, 4132-4135
40. W.-L. Jia, S. Vega Ces, M. Á. Fernández-Ibáñez, ''Divergent Total Syntheses of Yaequinolone-Related Natural Products by Late-Stage C–H Olefination'' J. Org. Chem. 2021, 86, 9, 6259-6277.
2020
39. V. Sukowski, M. Á. Fernández-Ibáñez, ''Switching from meta- to ortho-Selectivity by a Cyclometalated Ruthenium Catalyst'' Chem. 2020, 6, 6, 1209-1211.
2019
38. W.-L. Jia, N. Westerveld, K. M. Wong, T. Morsch, M. Hakkennes, K. Naksomboon, M. Á. Fernández-Ibáñez, ''Selective C–H Olefination of Indolines (C5) and Tetrahydroquinolines (C6) by Pd/S,O-Ligand Catalysis'' Org. Lett. 2019, 21(23), 9339-9342.
37. K. Naksomboon, J. Poater, F. M. Bickelhaupt, M. Á. Fernández-Ibáñez, "para-Selective C−H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis" J. Am. Chem. Soc. 2019, 141, 6719.
36. Y. Alvarez-Casao, M. Á. Fernández-Ibáñez, "S,O-Ligand-Promoted Pd-Catalyzed C-H Olefination of Thiophenes" Eur. J. Org. Chem. 2019, 8, 1842.
35. S. Kancherla, K. B. Jorgensen, M. Á. Fernández-Ibáñez "Recent Developments in Palladium-Catalysed Non-Directed C-H Bond Activation in Arenes” Synthesis, 2019, 51, 643.
2018
34. W.-L. Jia, M. Á. Fernández-Ibáñez, "Ligand‐Enabled γ‐C(sp3)‐H Acetoxylation of Triflyl‐Protected Amines" Eur. J. Org. Chem. 2018, 44, 6088. Special Issue: C-H Activation in Organic Synthesis [COST Action CA15106 (CHAOS)]
33. R. Solà, M. Veguillas,M. J. González-Soria, N. Carter, M. Á. Fernández-Ibáñez, B. Maciá, “Catalytic Enantioselective Addition of Organozirconium Reagents to Aldehydes” Molecules 2018, 23, 961. Special Issue: Stereogenic Centers
32. Y. Álvarez-Casao, C. A. M. R. van Slagmaat, G. K. M. Verzijl, L. Lefort, P. L. Alsters, M. Á. Fernández-Ibáñez, "Palladium-Catalyzed Cross-Dehydrogenative Coupling of o-Xylene: Evidence of a New Rate-Limiting Step in the Search for Industrially Relevant Conditions” Chem.Cat.Chem. 2018, 10, 2626.
31. K. Naksomboon, Y. Álvarez-Casao, M. Uiterweerd, N. Westerveld, B. Maciá, M. Á. Fernández-Ibáñez, "S,O-Ligand-promoted palladium-catalyzed C-H olefination of arenes with allylic substrates" Tetrahedron Lett. 2018, 59, 379.
2017
30. K. Naksomboon, C. Valderas, M. Gómez-Martínez, Y. Álvarez-Casao, M. Á. Fernández-Ibáñez, "S,O-Ligand-Promoted Palladium-Catalyzed C−H Functionalization reactions of Nondirected Arenes" ACS Catal. 2017, 7, 6342.
29. K. Naksomboon, C. Valderas, B. Macia, M. Á. Fernández-Ibáñez, "Synthesis of α-substituted diphenylphosphinocarboxylic acids and their palladium complexes"
Synlett, 2017, 28, 221.
2016
28. C. Valderas, K. Naksomboon, M. Á. Fernández-Ibáñez, "Ligand-Promoted Palladium-Catalyzed C-H Acetoxylation of Simple Arenes" Chem.Cat.Chem. 2016, 8, 3213.
27. M. Veguillas, R. Solà, M. Á. Fernández-Ibáñez, B. Maciá, “Catalytic enantioselective addition of methyltriisopropoxititanium to aldehydes” Tetrahedron: Asymmetry, 2016, 27, 643. 2016, 27, 643.
2014
26. M. Á. Fernández-Ibáñez,“Ligand Control Reactivity and Selectivity in Palladium-Catalyzed Functionalization of Unactivated C(sp3)-H Bonds” Chem. Cat. Chem. 2014, 6, 2188.
25. A. Poveda, I. Alonso, M. Á. Fernández-Ibáñez, “Experimental and Computational Studies on the Mechanism of Pd-Catalyzed C(sp3)-H g-Arylation of Amino Acid Derivatives assisted by the 2-Pyridylsulfonyl Group” Chem. Sci. 2014, 5, 3873.
24. A. K. Schoonen, M. Á. Fernández-Ibáñez, M. Fañanás-Mastral, J. F. Teichert, B. L. Feringa, “Chiral Amides via Copper-Catalyzed Enantioselective Conjugate Addition” Org. Biomol. Chem. 2014, 12, 36. (OBC Hot article)
2013
23. N. Rodríguez, J. A. Romero-Revilla, M. Á. Fernández-Ibáñez, J. C. Carretero, “Palladium-Catalyzed N-(2-pyridyl)sulfonyl-Directed C(sp3)-H g-Arylation of Amino Acid Derivatives”. Chem. Sci. 2013, 4, 175. (Highlighted in SYNFORM)
22. M. Á. Fernández-Ibáñez, B. Maciá, D. A. Alonso, I. M. Pastor “Recent Advances on the Catalytic Enantioselective Reformatsky Reaction” Eur. J. Org. Chem. 2013, 7028.
21. A. M. Valdivielso, P. Ventosa-Andrés, F. Tato, M. Á. Fernández-Ibáñez, I. Pappos; N. E. Tsopanoglou, M. T. García-López, M. Gutiérrez-Rodríguez, R. Herranz “ Highly functionalized 2-oxopiperazine-based peptidomimetics: An approach to PAR1 antagonists” Eur. J. Med. Chem. 2013, 70, 199.
20. M. Á. Fernández-Ibáñez, B. Maciá, D. A. Alonso, I. M. Pastor “Palladium and Organocatalysis: An excellent Recipe for Asymmetric Synthesis” Molecules, 2013, 18, 10108 (Invited Review).
2011
19. J. A. Romero-Revilla, A. García-Rubia, R. Gomez Arrayás, M. Á. Fernández-Ibáñez, J. C. Carretero, “Palladium-Catalyzed Coupling of Arene C-H Bonds with Methyl- and Arylboron Reagents Assisted by the Removable 2-Pyridylsulfinyl Group” J. Org. Chem. 2011 , 76, 9525.
18. A. García-Rubia, M. Á. Fernández-Ibáñez, R. Gómez Arrayás, J. C. Carretero “2-Pyridyl sulfoxide: a Versatile and Removable Directing Group for the Pd II-Catalyzed Direct C-H Olefination of Arenes”. Chem. Eur. J. 2011, 17, 3567. (VIP article).
2010
17. F. Sánchez-Sancho, J. A. Romero, M. Á. Fernández-Ibáñez, “e-Eros Encyclopedia of Reagents for Organic Synthesis (BENZYL CARBAMATE), Wiley-VCH Verlag GmbH & Co. KGaA, 2010.
16. P. H. Bos, B. Maciá, M. Á. Fernández-Ibáñez, A. J. Minnaard, B. L. Feringa “Catalytic asymmetric conjugate addition of dialkylzinc reagents to α,β-unsaturated sulfones”. Org. Biol. Chem. 2010, 8, 47.
2009
15. M. Á. Fernández-Ibáñez, B. Maciá, M. G. Pizzutti, A. J. Minnaard and B. L. Feringa “Catalytic Enantioselective Addition of Dialkylzinc Reagents to N-Acylpyridinium Salts”. Angew. Chem. Int. Ed. 2009, 48, 9339.
14. J. L. García Ruano, M. Á. Fernández-Ibáñez, J. A. Fernández-Salas, M. C. Maestro, P. Márquez-López, M. M. Rodríguez-Fernández “Remote Stereocontrol Mediated by a Sulfinyl Group: Synthesis of Allylic Alcohols via Chemoselective and Diastereoselective Reduction of g-Methylene d-Ketosulfoxides”. J. Org. Chem. 2009, 74, 1200.
2008
13. J. L. García Ruano, J. Alemán, M.B. Cid, M. Á. Fernández-Ibáñez, M. C. Maestro, M. R. Martín, A. M. Martín-Castro “Asymmetric Transformations Mediated by Sulfinyl Groups” In Organosulfur Chemistry in Asymmetric Synthesis (Ed. T. Toru, C. Bolm). Publisher: STM Books, Wiley-VCH Verlag GmbH & Co. KGaA, Boschstr. 2008, 12, 69469 Weinheim, Germany. ISBN: 9783527623235.
12. M. Á. Fernández-Ibáñez, B. Maciá, A. J. Minnaard, B. L. Feringa “Catalytic Enantioselecttive Reformatsky Reaction with ortho-Substituted Diaryketones”. Org. Lett. 2008, 10, 4041. (Highlighted in SYNFACTS).
11. M. Á. Fernández-Ibáñez, B. Maciá, A. J. Minnaard, B. L. Feringa “Catalytic Enantioselecttive Reformatsky Reaction with Ketones”. Chem. Commun. 2008, 2571.
10. B. Maciá, M. Á. Fernández-Ibáñez, N. Mršić, A. J. Minnaard, B. L. Feringa “Copper-catalyzed enantioselective conjugate addition of Grignard reagents to acyclic enones using monodentate phosphoramidite ligands”. Tetrahedron. Lett. 2008, 10, 1877.
9. M. Á. Fernández-Ibáñez, B. Maciá, A. J. Minnaard, B. L. Feringa “Catalytic Enantioselective Reformatsky Reaction with Aldehydes”. Angew. Chem. Int. Ed. 2008, 47, 1317.
2007
8. B. Maciá Ruiz, K. Geurts, M. Á. Fernández-Ibáñez, B. ter Horst, A. J. Minnaard, B. L. Feringa “Highly Versatile Enantioselective Conjugate Addition of Grignard Reagents to a,b-Unsaturated Thioesters”. Org. Lett. 2007, 24, 5123.
2006
7. J. L. García Ruano, M. Á. Fernández-Ibáñez, M. Carmen Maestro “Remote stereocontrol by sulfinyl group: Mukaiyama aldol reactions of ( S)-2-[2-(p-tolylsulfinyl)phenyl]acetaldehyde in the asymmetric synthesis of b-hydroxyacids and 1,3-diols”. Tetrahedron 2006, 62, 12297
6. J. L. García Ruano, M. Á. Fernández-Ibáñez, M. Carmen Maestro “Efficient trans-Selectivity in the Cyclocondensation of ( S)-2-[2-(p-Tolylsulfinyl)phenyl]acetaldehyde with Activated Dienes Catalyzed by Yb(OTf)3”. J. Org. Chem. 2006, 71, 7683.
5. J. L. García Ruano, M. Á. Fernández-Ibáñez, M. C. Maestro, M. M. Rodríguez-Fernández “Remote Stereocontrol by sulfinyl Groups: Hydrocyanation of d-Ketosulfoxides”. Tetrahedron 2006, 62, 1245.
2005
4. J. L. García Ruano, M. M. Rodríguez-Fernández, M. Á. Fernández-Ibáñez, M. C. Maestro “Remote Asymmetric Induction by Sulfoxide. DIBAL Reduction and Et 2AlCN Hydrocianation of ortho-( p-tolylsulfinyl)benzyl ketones”. Phosphorus Sulfur and Silicon. 2005, 180, 1495
3. J. L. García Ruano, M. Á. Fernández-Ibáñez, M. C. Maestro, M. M. Rodríguez-Fernández “Remote Stereocontrol by Sulfinyl Groups: Reduction of d-Ketosulfoxides”. J. Org. Chem. 2005, 70, 1796.
2004
2. J. L. García Ruano, J. Alemán, M. T. Aranda, M. Á. Fernández-Ibáñez, M. M. Rodríguez-Fernández and M. C. Maestro “Synthesis of chiral ortho-( p-tolylsulfinyl)benzyl ketones”. Tetrahedron 2004, 60, 10067.
2002
1. J. L. García Ruano, M. Á. Fernández-Ibáñez, A. M. Martín Castro, J. H. Rodríguez Ramos, A. C. Rubio Flamarique “Regio- and stereocontrolled hydrocyanation of chiral 2-alkylglycidamides with Et 2AlCN: synthesis of enantiomerically pure mono- and disubstituted malic acid derivatives”. Tetrahedron: Asymmetry 2002, 13, 1321.
